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Novel binding mode for fluorinated porphyrins: synthesis and fluorophilic affinity of stable atropoisomers of 5,10,15,20-tetrakis[2-(perfluoroacyl)aminophenyl]-21H,23H-porphyrins

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
43
Issue
38
Identifiers
DOI: 10.1016/s0040-4039(02)01513-7
Disciplines
  • Chemistry

Abstract

Abstract The synthesis and binding properties of 5,10,15,20-tetrakis[2-(perfluoroacyl)aminophenyl]-21 H,23 H-porphyrins as new types of fluorophilic receptors for potential application as optical sensors are reported. The observed remarkable binding affinity for fluorinated substrates monitored by vis spectroscopy represents a novel binding mode in porphyrin chemistry.

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