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Conformational study of CH3OP(O)Cl2and CD3OP(O)Cl2:Part 3. Low-temperature solid state and matrix isolation study

Authors
Journal
Journal of Molecular Structure
0022-2860
Publisher
Elsevier
Publication Date
Volume
125
Identifiers
DOI: 10.1016/0022-2860(84)85023-1

Abstract

Abstract The FIR, MIR and Raman spectra of methoxy dichlorophosphinoxide and its deuterated analogue in the low-temperature solid state and the low-temperature matrix isolation MIR spectra of the normal compound have been recorded. The previously published assignment of the deformation modes is slightly revised. The trans conformer was found to be the only conformer left in the annealed solid state while the conformational distribution trapped in the matrices is similar to the gas-phase equilibrium.

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