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Methanol adsorption and decomposition on (2 × 1)Pt(110): enhanced stability of the methoxy intermediate on a stepped surface

Surface Science
Publication Date
DOI: 10.1016/0039-6028(91)90358-y


Abstract The decomposition of methanol on (2 × 1)Pt(110) is examined using TPD and EELS. It is found that the methanol adsorbs molecularly at 100 K. Some of the methanol desorbs upon heating to 125–200 K and some decomposes to yield methoxy (μ-OCH 3). Upon further heating to 215–275 K some of the methoxy recombines with hydrogen to yield methanol and some decomposes to yield CO and hydrogen. There is also the hint of a transient intermediate at 220 K which has characteristics consistent with formaldehyde (CH 2=O ab) or a formyl (−CH=O ab) species. A comparison with the previous literature indicates that the decomposition of the methoxy intermediate is much slower on (2 × 1)Pt(110) than on Pt(111) even though there are (111) terraces on (2 × 1)Pt(110). Thus. this paper demonstrates for the first time that steps can decrease the rate of a simple decomposition reaction.

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