Affordable Access

Two New Supramolecular Assemblies Obtained by Reaction Between Saccharin and Long-chain Diamines

Authors
Journal
Zeitschrift für Naturforschung B
0932-0776
Publisher
Verlag der Zeitschrift fuer Naturforsch
Publication Date
Keywords
  • Heptamethylenediammonium Bis(Saccharinate) Monohydrate
  • Octamethylenediammonium Bis(Saccharinate) Hemihydrate
  • Crystal Structures
  • Supramolecular Adducts
  • Ir Spectra

Abstract

The crystal Structures of heptamethylenediammonium bis(saccharinate) monohydrate, [H(3)N-(CH(2))(7)-NH(3)](sac)(2)center dot H(2)O (1) 0 (1) and octamethylenediammonium bis(saccharinate) hemihydrate, [H(3)N-(CH(2))(8)-NH(3)](sac)(2)center dot 0.5H(2)O (2), were determined-by single-crystal X-ray diffraction methods. Compound I crystallizes in the triclinic space group P (1) over bar with 2 molecules per unit cell, and 2 in the monoclinic space group P2(1)/a with Z = 4. The saccharinate moiety is planar in both compounds presenting bonding characteristics comparable to those found in other saccharinate salts. The ionic crystals are further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional Supramolecular assembly. The FTIR spectra of the adducts are briefly discussed in comparison with those of the constituent Molecules.

There are no comments yet on this publication. Be the first to share your thoughts.