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Photoelectron spectra and molecular properties:XX. Dimethyl ether, methoxysilane, and disiloxane

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
61
Identifiers
DOI: 10.1016/s0022-328x(00)86540-7
Disciplines
  • Mathematics

Abstract

Abstract The photoelectron (PE) spectra of methyl and silyl ethers are assigned and correlated on the basis of CNDO/2-SCF-MO calculations. The dynamic behavior of the individual orbitals is discussed in terms of electronic and geometric perturbations of the ether system.

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