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Phospha-S-triazines. IX. Chloro-substituted monophospha-S-triazines and derivatives

Authors
Journal
Journal of Fluorine Chemistry
0022-1139
Publisher
Elsevier
Publication Date
Volume
28
Issue
4
Identifiers
DOI: 10.1016/s0022-1139(00)81134-3

Abstract

Abstract 1-Dichlorophospha-3,5-bis(perfluoro-n-heptyl)-2,4,6- triazine and one of its perfluoroalkylether analogues were synthesized by interaction of phosphorus pentachloride with the respective imidoylamidines; subsequent replacement of the chloro- by azido groups proceeded readily. 1-Chloro(phenyl)- phospha-3,5-bis(perfluoro-n-heptyl)-2,4,6-triazine was prepared by a parallel process using tetrachlorophenylphosphorane instead of phosphorus pentachloride; phenoxy and stearyloxy derivatives were formed without difficulty. All the compounds, with the exception of 1-stearyloxy(phenyl)phospha-3,5-bis(perfluoro- n-heptyl)-2,4,6-triazine, exhibited the characteristic mass spectral fragmentation patterns associated with the monophospha- s-triazine ring system.

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