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Stereoselectivity and exciton cotton effects in mixed complexes of zinc(II)

Authors
Journal
Journal of Inorganic and Nuclear Chemistry
0022-1902
Publisher
Elsevier
Publication Date
Volume
43
Issue
11
Identifiers
DOI: 10.1016/0022-1902(81)80616-1

Abstract

Abstract Mixed complexes of Zn(II) with chiral aminoacids and 1,10-phenanthroline have been prepared and their C.D. and O.R.D. spectra measured. All the C.D. spectra exhibited an exciton splitting at 268 nm and their intensities depended on the chiral ligand. These results were interpreted in terms of steric effects through the exciton theory.

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