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Anharmonicities in the theory of non-radiative transitions for polyatomic molecules

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
11
Issue
5
Identifiers
DOI: 10.1016/0009-2614(71)87007-0

Abstract

Abstract A dynamic theory for non-radiative transitions is presented which treats anharmonic potentials and interactions between normal modes. The amount of energy which flows into a certain vibrational mode of a typical hydrocarbon is determined and the participation of the anharmonicities is analyzed.

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