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Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline-κ2 P,N}platinum(II)

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
67
Issue
11
Identifiers
DOI: 10.1107/s1600536811040098
Source
Legacy
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

The title compound, [PtCl2(C31H32NP)], is a PtII complex with an NPCl2 coordination sphere in which the PtII atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P—Pt—N angle is 89.80 (5)° and the corresponding angle between the Cl ions is 87.92 (2)°.

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