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A copper (III) periodate peroxo complex: K4H4Cu(IO6)2O2· 6H2O

Authors
Journal
Journal of Solid State Chemistry
0022-4596
Publisher
Elsevier
Publication Date
Volume
73
Issue
1
Identifiers
DOI: 10.1016/0022-4596(88)90070-9
Disciplines
  • Chemistry

Abstract

Abstract The chemical preparation and crystal structure of the trivalent copper salt K 4H 4Cu(IO 6) 2O 2 · 6H 2O are described. Crystals are monoclinic (space group P2 1 n ; a = 12.650(2), b = 9.780(2), c = 7.710(2) Å, β = 95.2°(1), Z = 2). The structure is refined until R = 0.038 for 2223 reflections. Isolated Cu(IO 6) 7− 2 units and O − 2 superoxide groups occur. In the Cu(IO 6) 7− 2 unit, the trivalent copper ion is surrounded by four oxygen atoms in a rectangular configuration.

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