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The Michael reaction of acetophenones withtrans-dibenzoylethylene

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
53
Issue
3
Identifiers
DOI: 10.1016/s0040-4020(96)01028-9
Disciplines
  • Physics

Abstract

Abstract The synthesis of a series of highly substituted cyclohexane derivatives has been carried out in a single one-pot reaction of aceteophenones and trans-dibenzoylethylene (1:2) using sodium ethoxide in anhydrous diethyl ether at room temperature to give 4-aroyl-2,3,5-tribenzoyl-1-phenylcyclohexanols. A structural assignments was achieved from the elemental analysis, infrared, and proton nuclear magnetic resonance spectroscopy. The single crystal x-ray crystallography clearly shows the highly substituted cyclohexane ring.

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