Affordable Access

Improved synthesis of [closo-1-CB9H10]– anion and new C-substituted derivatives

Authors
Publisher
Institute of Organic Chemistry and Biochemistry
Publication Date

Abstract

The Brellochs method was utilized to gain access to the [closo-1-CB9H10]– anion (1). Previous work describing the details of the synthesis of 1 via the [closo-2-CB9H10]– anion (2) was brief and insufficient. Therefore, we report an optimized procedure for the synthesis of 1, the preparation of the unknown C-halogenated series using N-halosuccinimides and bis(benzenesulfonyl)fluoroamine, and the unknown C-methylated product using CH3I. NMR properties and regularities within the series were also investigated.

There are no comments yet on this publication. Be the first to share your thoughts.

Statistics

Seen <100 times
0 Comments