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Single-ion approach to the susceptibility of an intermediate valence compound paramagnetic Imse

Authors
Journal
Solid State Communications
0038-1098
Publisher
Elsevier
Publication Date
Volume
30
Issue
5
Identifiers
DOI: 10.1016/0038-1098(79)90077-2
Disciplines
  • Physics

Abstract

Abstract The magnetic properties of an intermediate valence compound are discussed within a single-ion framework. The effects of configuration mixing, crystalline electric fields, and external magnetic fields are included in the hamiltonian. The method incorporates in one single consistent approach both coherent (quantum) and incoherent (thermal) fluctuations. Numerical evaluation of the susceptibility and field dependent magnetization with parameters appropriate for TmSe yields results in good agreement with experiment.

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