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NaHSO4supported on silica gel: an alternative catalyst for Ferrier rearrangement of glycals

Authors
Journal
Carbohydrate Research
0008-6215
Publisher
Elsevier
Publication Date
Volume
346
Issue
16
Identifiers
DOI: 10.1016/j.carres.2011.08.023
Keywords
  • Nahso4
  • Silica Gel
  • Ferrier Rearrangement
  • Glucal
  • Glycoside

Abstract

Abstract NaHSO 4 supported on silica gel catalyses the Ferrier rearrangement reaction of 3,4,6- tri- O-acetyl- d-glucal with alcohols and thiols to give the corresponding 2,3-unsaturated glycosides in high anomeric selectivity and good to excellent yield in short reaction time.

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