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Electrochemical parameterization of 1,1′-disubstituted cobaltocenium compounds

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
750
Identifiers
DOI: 10.1016/j.jorganchem.2013.11.016
Keywords
  • Cyclic Voltammetry
  • Electrochemistry
  • Cobaltocenium
  • Ferrocene
  • X-Ray Structure
Disciplines
  • Chemistry

Abstract

Abstract Two new 1,1′-disubstituted cobaltocenium compounds, [(C5H4CHEt2)2Co][PF6] and [(C5H4SiMe3)2Co][PF6], were synthesized and the X-ray crystal structures were determined. The electrochemistry of seven 1,1′-disubstituted cobaltocenium compounds and the analogous ferrocene compounds was studied in methylene chloride using cyclic voltammetry. The affect of the various substituents on the redox potentials of these compounds was examined and trends in the electrochemical data were explored.

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