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Poly[aqua­(μ3-pyridazine-4-carboxyl­ato-κ2 O:O:O′)lithium]

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
67
Issue
4
Identifiers
DOI: 10.1107/s1600536811008634
Source
Legacy
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

The structure of the title compound, [Li(C5H3N2O2)(H2O)]n, is composed of centrosymmetric dimers in which two LiI ions are bridged by a carboxyl­ate O atom, each donated by a ligand, acting in a bidentate mode. The second carboxyl­ato O atoms bridge the dimers to LiI ions in adjacent dimers, forming mol­ecular layers parallel to (001). Each LiI ion is coordinated by two bridging carboxyl­ate O atoms, a bridging carboxyl­ate O atom donated by the adjacent dimer and an aqua O atom, resulting in a distorted tetra­hedral coordination geometry. The layers are held together by O—H⋯N hydrogen bonds in which coordinated water O atoms act as donors and ligand hetero-ring N atoms as acceptors.

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