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Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)]

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
66
Issue
4
Identifiers
DOI: 10.1107/s1600536810010196
Keywords
  • Metal-Organic Papers

Abstract

The title compound, (C21H22P)2[Cu2I4], prepared from reaction between copper powder, iodine and isopropyl triphenyl­phospho­nium iodide in hydroxy­acetone (acetol), shows an already known Cu2I4 2− anion with a planar conformation [Cu—I range = 2.5108 (3)–2.5844 (3) Å and I—Cu—I range = 110.821 (10)–125.401 (10)°].

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