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Full Functionalization of the Thieno[3,2-b]thiophene Scaffold. Benzo[b]thiophenes via Intramolecular Carbomagnesiation of Alkynyl(aryl)thioethers. Preparation and Reactions of Solid Organozinc Reagents.

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Ludwig-Maximilians-Universität München
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  • Fakultät Für Chemie Und Pharmazie

Abstract

Full Functionalization of the Thieno[3,2-b]thiophene Scaffold. Benzo[b]thiophenes via Intramolecular Carbomagnesiation of Alkynyl(aryl)thioethers. Preparation and Reactions of Solid Organozinc Reagents. Dissertation zur Erlangung des Doktorgrades der Fakultät für Chemie und Pharmazie der Ludwig-Maximilians-Universität München Full Functionalization of the Thieno[3,2-b]thiophene Scaffold. Benzo[b]thiophenes via Intramolecular Carbomagnesiation of Alkynyl(aryl)thioethers. Preparation and Reactions of Solid Organozinc Reagents von Thomas Kunz aus München 2011 Erklärung Diese Dissertation wurde im Sinne von § 13 Abs. 3 bzw. 4 der Promotionsordnung vom 29. Januar 1998 (in der Fassung der sechsten Änderungssatzung vom 16. August 2010) von Professor Dr. Paul Knochel betreut. Ehrenwörtliche Versicherung Diese Dissertation wurde selbständig und ohne unerlaubte Hilfe bearbeitet. München, 28. September 2011 ___________________ Thomas Kunz Dissertation eingereicht am: 30. September 2011 1. Gutachter: Prof. Dr. Paul Knochel 2. Gutachter: Prof. Dr. Manfred Heuschmann Mündliche Prüfung am: 7. November 2011 This work was carried out from September 2009 to August 2011 under the guidance of Prof. Dr. Paul Knochel at the Department of Chemistry of the Ludwig-Maximilians-Universität Munich. First of all, I thank Prof. Dr. Paul Knochel for accepting me as a PhD student in his group, for his support and advice in the course of my research and for his interest in this work. I would like to express my appreciation to Prof. Dr. Manfred Heuschmann for agreeing to be second reviewer of this thesis and I thank all members of my defense committee – Prof. Dr. Konstantin Karaghiosoff, Prof. Dr. Heinz Langhals, Prof. Dr. Thomas Bein and Prof. Dr.

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