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Kinetics of the cis-trans isomerisation of cyclopropanes : comparison between capto-dative and di-capto radical stabilisation

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
24
Issue
27
Identifiers
DOI: 10.1016/s0040-4039(00)88016-8

Abstract

Abstract Capto-dative ( cd) ( c = CN, d = OR, SR, NR 2) compared to di-capto substitution ( c = CN, c′ = COOR) was found to be more efficient in lowering the activation energy of cis-trans isomerisation of cyclopropanes.

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