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Long-range interactions of Li(n= 2) states with each other and the long-range interaction of Li(2s2S) with Li(3s2S)

Authors
Journal
Chemical Physics
0301-0104
Publisher
Elsevier
Publication Date
Volume
77
Issue
3
Identifiers
DOI: 10.1016/0301-0104(83)85098-8

Abstract

Abstract We compute and analyze the potential energy for the twenty-six lowest-lying states of Li 2 which correspond asymptotically to the interaction of Li(2s 2S) with Li(2s 2S). Li(2p 2P) or Li(3s 2S), and the interaction Li(2p 2P) with Li(2p 2P) to obtain the leading terms of the first-order electrostatic energies, and the second-order dispersion energies. Ion-pair perturbations are found to dominate the potential curves of several states. The polarizabilities of Li 2s, 2p and 3s in various fields are calculated.

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