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Effect of doping an organic molecule ligand on TGS single crystals

Authors
Journal
Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy
1386-1425
Publisher
Elsevier
Publication Date
Volume
71
Issue
2
Identifiers
DOI: 10.1016/j.saa.2007.11.039
Keywords
  • Triglycinesulphate
  • X-Ray Diffraction
  • Ftir
  • Optical Transmission
  • Second Harmonic Generation

Abstract

Abstract Good quality single crystals of thiourea-doped triglycinesulphate (TuTGS) a new semiorganic nonlinear optical (NLO) crystal has been successfully grown from aqueous solution by slow evaporation method. The solubilities under various solvents in different proportions have been studied. The structural characterization of the grown crystals was carried out by X-ray diffraction. The grown crystals were subjected to FTIR and Raman analyses for vibrational assignments. The optical absorption coefficient α was analysed and interpreted to be allowed in the direct transition. The values of allowed direct energy gap ( E g) for undoped and doped crystals were calculated. It was found that E g values were decreased with organic molecule doping. The powder technique of Kurtz and Perry confirm the NLO property of the grown crystal.

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