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Synthesis of triphenylphosphine-functionalized dendrimers and application to olefin hydroformylation

Authors
Journal
Journal of Molecular Catalysis A Chemical
1381-1169
Publisher
Elsevier
Publication Date
Volume
227
Identifiers
DOI: 10.1016/j.molcata.2004.10.009
Keywords
  • Dendritic Catalyst
  • Hydroformylation
  • Triphenylphosphine
  • Dendrimer
  • Convergent Method

Abstract

Abstract A new class of dendrimers functionalized with triphenylphosphines at the periphery has been synthesized by using convergent method. These dendritic ligands were successfully applied to rhodium-catalyzed hydroformylation of olefin. Similar regioselectivity and reactivity were obtained for the dendritic systems and the parent compound.

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