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Rate of recombination of trichloromethyl radicals in the gas phase

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
1
Issue
2
Identifiers
DOI: 10.1016/0009-2614(67)80071-x

Abstract

Abstract The rate constant for the recombination of trichloromethyl radicals has been measured in the gasphase photochlorination of chloroform at 344.7°K. The observed value is 10 9.62 mole -1 1 sec -1, much lower than the value predicted by transition state calculations using Gorin's model.

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