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Intermolecular reduction of CO by iron and molybdenum hydrides

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
260
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)98683-2

Abstract

Abstract Fp′H ( 2, Fp′ = C 5(CH 3) 5Fe(CO) 2) reduces Fp′(CO) +PF 6 − ( 1) to Fp′CH 2OH ( 4 and further to Fp′CH 3 ( 5) and gives Fp′(THF) +PF 6 − ( 6) which, under CO recycles the active complex 1; H 4Mo(dppe) 2 reduces 1 to Fp′ 2 and 4, consistent with the abilities of the Lewis acids to bind the formyl intermediate (BH 3 > M 3Mo(dppe) 2 + > Fp′ +).

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