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1-Phenylethenol: The enol form of acetophenone. Preparation, ionization energy and the heat of formation in the gas phase

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
27
Issue
35
Identifiers
DOI: 10.1016/s0040-4039(00)84955-2

Abstract

Abstract The enol form of acetophenone was generated in the gas phase and its ionization energy was determined as 8.01 ± 0.03 eV. The heat of formation of the enol was assessed as −46 ± 6 kJ.mol −1. The enol is destabilized against acetophenone by 41 kJ.mol −1.

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