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A new chiral multidentate ligand for asymmetric catalysis

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
36
Issue
26
Identifiers
DOI: 10.1016/0040-4039(95)00844-3

Abstract

Abstract The synthesis of enantiomerically pure ( R,R)-N,N′-bis(3-diphenylphosphino-2-hydroxybenzylidene)-1,2-diphenyl-1,2-ethanediamine ( 1) is described. This multidentate salentype ligand offers several possibilities for the construction of chiral mono-nuclear or bi-nuclear metal complexes, which may be useful in bifunctional asymmetric catalysis.

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