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Synthesis of α-substituted α,β-unsaturated acylsilanes

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
39
Issue
33
Identifiers
DOI: 10.1016/s0040-4039(98)01219-2
Keywords
  • Allenes
  • Acyl Silanes
  • Rearrangement

Abstract

Abstract α-Deprotonation of tert-butyldimethylsilyloxy allene is followed by silyl migration from oxygen to carbon. The resulting C-nucleophile adds to aldehydes to generate α,β-unsaturated acylsilanes.

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