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A new 5,6-dihydro-2H-1,3-oxazine synthesis via Asigner-type condensation

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
49
Issue
42
Identifiers
DOI: 10.1016/s0040-4020(01)80219-2

Abstract

Abstract In this article - which we dedicate to the lifework 1 of Professor Teruaki Mukaiyama - a new general 5,6-dihydro- 2H-1,3-oxazine synthesis is described. 3-Hydroxy-2,2-dimethylpropionaldehyde is condensed with a second oxo component and ammonia to the title compound in several examples. In the case of citronellal diastereoselectivity is observed.

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