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The contributions to the electronic factor in bridge-assisted electron transfer processes

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
140
Issue
1
Identifiers
DOI: 10.1016/0009-2614(87)80417-7

Abstract

Abstract We present a new formulation of the various contributions to the electronic factor of bridge-assisted electron transfer rates, which explicitly takes into account the many-electron character of the wavefunctions and the overlap integrals between adjacent orbitals. Aside from superexchange terms, this formulation focuses on an important new multiple-exchange contribution.

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