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Novel and efficient synthesis of perfluoroalkylated arylphosphines

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
41
Issue
19
Identifiers
DOI: 10.1016/s0040-4039(00)00445-7
Keywords
  • Perfluoroalkylated Phosphines
  • Copper-Mediated Coupling
  • Arylphosphines

Abstract

Abstract A novel, high-yield route has been developed for the synthesis of perfluoroalkylated arylphosphines, involving simple, copper-mediated coupling of haloarylphosphine oxides with perfluoroalkyl iodides followed by reduction with trichlorosilane.

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