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Rhodium-catalyzed coupling reaction of 2-vinylpyridines with 1,5-hexadiene: effects of phosphine ligands

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
40
Issue
43
Identifiers
DOI: 10.1016/s0040-4039(99)01550-6
Keywords
  • Coupling Reaction
  • CH Bond Activation
  • Rhodium Catalyst

Abstract

Abstract The coupling reaction of 2-isopropenylpyridine with 1,5-hexadiene via CH bond activation gave different products depending on the ligands: triphenylphosphine as a ligand led to the cyclized products and trimethylphosphite to the Markovnikov addition product.

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