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Reactions ofcis-hydridotetracarbonyl(triphenylphosphine)manganese with some organic halogen compounds

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
43
Issue
2
Identifiers
DOI: 10.1016/s0022-328x(00)81613-7

Abstract

Abstract The hydride cis-HMn(CO) 4PPh 3 is an effective reagent for the reduction of a variety of halogenated organic compounds at room temperature. All the available evidence indicates that these reactions occur by a free radical mechanism.

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