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Diode Laser Spectrum of the ν1Fundamental Band of PNO

Authors
Publisher
Elsevier Inc.
Publication Date
Volume
211
Issue
1
Identifiers
DOI: 10.1006/jmsp.2001.8487

Abstract

Abstract The diode laser spectrum of the ν 1 fundamental band of the short-lived molecule PNO has been detected with 59 R- and P-branch lines accurately measured. The lines were unambiguously assigned using the rotational and distortion constants for the ground and (100) vibrational levels found previously by microwave spectroscopy. The band origin was determined to be 860.301 228(31) cm −1 from a one parameter fit. The gas phase band origin is red-shifted by approximately 4 cm −1 from the matrix value.

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