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Titration of vanadium(IV) with cerium(IV) sulphate, with ferroin as indicator, in aqueous acetone as facile reaction medium:An analytical and mechanistic study

Authors
Journal
Talanta
0039-9140
Publisher
Elsevier
Publication Date
Volume
28
Issue
5
Identifiers
DOI: 10.1016/0039-9140(81)80164-6

Abstract

Abstract A new procedure for the titration of vanadium(IV) with cerium(IV) sulphate, with ferroin as indicator, in aqueous acetone medium is reported. A differential determination of iron(II) and vanadium(IV) is also possible. A probable mechanism for the fast ferriin—vanadium(IV) reaction in acetone medium is given.

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