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Reaction of pentacarbonyliron with a nitrogen heterocycle. X-ray crystal structure of bis[(carbonyl)(quinoline-2-thiolate-N,S)]iron(II)

Authors
Journal
Polyhedron
0277-5387
Publisher
Elsevier
Publication Date
Volume
12
Issue
3
Identifiers
DOI: 10.1016/s0277-5387(00)81727-1
Disciplines
  • Mathematics

Abstract

Abstract The monomeric compound bis[(carbonyl)(quinoline-2-thiolate-N,S)]iron(II) was synthesized and studied by IR and Mössbauer spectroscopy, cyclic voltammetry and X-ray diffraction. The molecule has two terminal carbonyl groups and two quinoline-2-thiolate anions coordinated as N,S-donor chelates, and the iron atom shows an octahedral coordination geometry.

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