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Ptaquilosin, the aglycone of a bracken carcinogen ptaquiloside: Chemical derivation from ptaquiloside and the reactivity

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
45
Issue
9
Identifiers
DOI: 10.1016/s0040-4020(01)80086-7
Disciplines
  • Chemistry

Abstract

Abstract From a bracken carcinogen ptaquiloside (2), the aglycone ptaquilosin (1) has been prepared by a series of chemical reactions. Action of weak base on ptaquilosin (1) caused dehydration to generate the highly reactive dienone (3) the ultimate form of 2.

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