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Structural and conformational studies on citreoviridinol and isocitreoviridinol: syntheses of some 2,6-dioxabicyclo[3.2.1]octanes

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
26
Issue
27
Identifiers
DOI: 10.1016/s0040-4039(00)98162-0
Disciplines
  • Chemistry

Abstract

Abstract Isocitreoviridinol has been newly isolated from the mycelium of Penicillium citreo-viride B. (IFO 6050) together with citreoviridinol, and their stereostructures have also been elucidated by means of chemical method: the 2,6-dioxabicyclo[3.2.1]octanes have been made, one of which is regarded as a promising synthetic intermediate of citreoviridinol. In addition, isocitreoviridinol diacetate has been derived from citreoviridin in 3 steps.

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