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Complexation of poly(pyrrole-EDTA like) film modified electrodes: Application to metal cations electroanalysis

Authors
Journal
Electrochimica Acta
0013-4686
Publisher
Elsevier
Publication Date
Volume
52
Issue
9
Identifiers
DOI: 10.1016/j.electacta.2006.09.041
Keywords
  • Functionalized Polypyrrole
  • Imprinted Polymer
  • Stripping Voltammetry
  • Competitive Complexation
  • Metal Ions Analysis
Disciplines
  • Chemistry

Abstract

Abstract Complexing polymer-coated electrodes have been synthesized by oxidative electropolymerization of N, N′-ethylene bis[ N-[(3-(pyrrole-1-yl)propyl) carbamoyl) methyl]-glycine] ( L). There were used for the electrochemical detection of Cu(II), Pb(II) and Cd(II) ions by means of the chemical preconcentration-anodic stripping technique. For thick polymeric binding materials and long accumulation times, competitive experiments showed that the poly L film modified electrodes are selective towards Cu(II) ions and particularly insensitive to the presence of Cd(II). In contrast, imprinted polymer-coated electrodes prepared by electropolymerization of the Cd(II) complex of L allowed an efficient complexation and sensing of Cd(II) cations. The selectivity of the molecular electrode materials can thus be subtly modulated upon playing on the accumulation time and on the pre-structuration of the complexing polymers.

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