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Anion exchange of metal complexes—XXI Sorption of uranyl chloride from anhydrous methanolic, ethanolic and isopropanolic hydrogen chloride solution

Authors
Journal
Journal of Inorganic and Nuclear Chemistry
0022-1902
Publisher
Elsevier
Publication Date
Volume
40
Issue
3
Identifiers
DOI: 10.1016/0022-1902(78)80440-0

Abstract

Abstract The distribution of dioxouranium(VI) (uranyl) ions at low concentrations between Dowex-IX8-Cl and solutions of hydrogen chloride in methanol, ethanol and 2-propanol ( iso-propanol) was studied under nearly completely anhydrous conditions, and in the presence of 1% by volume of water. The results are consistent with the presence in the external solutions of UO 2Cl +, UO 2Cl 2 and ion-paired H +UO 2Cl 3 −, and in the resin phase of UO 2Cl 2 (not reacting with R +Cl − or H +Cl −) as the main uranyl species.

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