Affordable Access

Publisher Website

The synthesis and stereoselective conjugate addition reactions of α-alkoxyorganocuprate reagents

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
27
Issue
38
Identifiers
DOI: 10.1016/s0040-4039(00)85001-7
Disciplines
  • Chemistry

Abstract

Abstract α-Alkoxyorganocuprate reagents have been prepared from α-alkoxyorganostannanes. The cuprates undergo diastereoselective conjugate addition reactions with cyclohexenone with up to 8:92 selectivity. The effects of trimethylsilyl chloride on the chemical yields and the diastereoselectivity of the reaction are described.

There are no comments yet on this publication. Be the first to share your thoughts.