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Calix(4)arene metal complexes as nuclease and transacylase mimics

University of Twente
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Supramolecular catalysis is the main topic of this thesis. New calix[4]arene-based metallo-catalysts were synthesized by linking one, two or three ligating groups at the upper rim of the calixarene skeleton. The catalytic activity of the copper, zinc or barium complexes was investigated in phosphoryl and acyl transfer reactions.

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