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Physical properties of the cation-mixed M′MPS3phases

Authors
Journal
Materials Research Bulletin
0025-5408
Publisher
Elsevier
Publication Date
Volume
35
Issue
11
Identifiers
DOI: 10.1016/s0025-5408(00)00384-6
Keywords
  • A. Chalcogenides
  • A. Layered Compounds
  • D. Magnetic Properties

Abstract

Abstract The cation-mixed compounds Cd 0.5Fe 0.5PS 3, Cd 0.5Mn 0.5PS 3, Fe 0.5Mn 0.5PS 3, and Fe 0.5Ni 0.5PS 3 have been synthesized from the corresponding elements at 1023 K. These compounds have been characterized by powder X-ray diffraction, conductivity, and magnetic susceptibility measurements. The conductivity at room temperature of the M′MPS 3 phases lies between the conductivity values for the corresponding end-member phases MPS 3. The magnetic measurements show that the magnetic interaction of the MPS 3 phases is retained in the mixed phases, but the magnetic order is weakened due to the disordered arrangements of the metal ions in M′MPS 3 phases.

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