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Spectroscopic studies on vanadyl ion in rubidium magnesium sulphate hexahydrate

Authors
Journal
Solid State Communications
0038-1098
Publisher
Elsevier
Publication Date
Volume
53
Issue
8
Identifiers
DOI: 10.1016/0038-1098(85)90380-1

Abstract

Abstract The optical absorption spectrum of VO 2+ ion in a single crystal of Rb 2Mg(SO 4) 26H 2O has been investigated both at laboratory and liquid nitrogen temperatures. The electron paramagnetic resonance (EPR) spectrum of the polycrystalline sample has also been investigated at the laboratory temperature. Both optical absorption and EPR spectra are characteristic of the VO 2+ ion in tetragonal symmetry. Molecular orbital coefficients have been evaluated by correlating the optical absorption and EPR data.

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