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The one-dimensional Van der Waals gas

Authors
Publisher
Elsevier B.V.
Publication Date
Volume
48
Issue
3
Identifiers
DOI: 10.1016/0031-8914(70)90241-7

Abstract

Abstract The Van der Waals gas with long but finite attractive potential is studied in one dimension. The exponent of the integrand in the partition function is expanded to fourth order (“third Van der Waals approximation‘). The fourth-order term has the effect of rounding off the singularity at the Van der Waals critical point, and replacing it with a rather sharp but analytic transition.

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