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Raman spectra and structure of bismuth iodide complexes

Authors
Journal
Journal of Molecular Structure
0022-2860
Publisher
Elsevier
Publication Date
Volume
3
Identifiers
DOI: 10.1016/0022-2860(69)87027-4

Abstract

Abstract The complex ions formed between bismuth triiodide and iodide ions in acetone solution have been studied by Raman Spectroscopy. The (BiI 4) − ion appears to have C 2v symmetry, suggesting a trigonal bipyramidal structure with one equatorial position occupied by a lone pair. The (BiI 6) 3− ion appears to be octahedral in solution and in the crystalline state. No evidence was found for the formation of complex ions other than these two species.

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