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Hydroalkylation of benzene and ethylbenzene over metal containing zeolite catalysts

Authors
Journal
Microporous and Mesoporous Materials
1387-1811
Publisher
Elsevier
Publication Date
Volume
105
Identifiers
DOI: 10.1016/j.micromeso.2007.05.058
Keywords
  • Hydroalkylation Of Benzene And Ethylbenzene
  • Zeolites Mcm-22
  • Bea

Abstract

Abstract The reaction of benzene and ethylbenzene has been studied over Ru/Ni/Beta and Ru/Sn/MCM-22 under 0.2–1 MPa, in the temperature range of 150–230 °C and WHSV of 2–64 h −1. The main reaction pathways included benzene and ethylbenzene hydrogenation towards cyclohexane and ethylcyclohexane, hydroalkylation into cyclohexylbenzene, ethylcyclohexylbenzenes and diethylcyclohexylbenzenes and formation of ethylbiphenyls or diethylbiphenyls followed by hydrogenation. The major reaction products were para- and meta-ethylcyclohexylbenzenes. The best catalyst performance was obtained over Ru/Ni/Beta at 170 °C, 1 MPa, WHSV of 2 h −1 and H 2/benzene/ethylbenzene = 2/1/1. The conversion of benzene and ethylbenzene over this catalyst was 78%, while selectivity to ethylcyclohexylbenzene amounted to 42%.

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