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A possibility of orthorhombic Jahn-Teller distortion

Authors
Journal
Journal of Physics and Chemistry of Solids
0022-3697
Publisher
Elsevier
Publication Date
Volume
31
Issue
10
Identifiers
DOI: 10.1016/0022-3697(70)90235-0

Abstract

Abstract A possibility has been investigated that an octahedral complex, having sufficiently isolated triply degenerate electronic state, undergoes an orthorhombic distortion through Jahn-Teller effect linear and quadratic in vibrational T 2 mode. Effects of vibrational E mode are assumed to be small compared with those of T 2 mode and are neglected. The inclusion of the quadratic effects leads to the stable potential minima which stabilize the orthorhombic distortion for suitable conditions.

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