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Significance and experimental determination of stoichiometric number

Authors
Journal
Journal of Catalysis
0021-9517
Publisher
Elsevier
Publication Date
Volume
1
Issue
3
Identifiers
DOI: 10.1016/0021-9517(62)90048-9
Disciplines
  • Mathematics

Abstract

Abstract The concept of Stoichiometric number is introduced with special reference to the applicability of the classical theorem k′ k″ = K to the relation between the forward and the backward rate constants, k′ and k″, and the equilibrium constant K. The significance of the Stoichiometric number ν r of the rate-determining step in determining the mechanism is illustrated. The theoretical background of ν r and theorems on ν r derived from its definition are reviewed and on their basis the experimental determination of ν r is illustrated in several cases.

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