Affordable Access

Molybdenum/cobalt/sulfur clusters: Models and precursors for hydrodesulfurization (HDS) catalysts

Authors
Journal
Applied Organometallic Chemistry
0268-2605
Publisher
Wiley Blackwell (John Wiley & Sons)
Publication Date

Abstract

Sulfido clusters which incorporate molybdenum and a late transition metal, e.g. iron, cobalt or nickel, are readily prepared by the reactions of Cp 2 Mo 2 S 4 , Cp 2 Mo 2 S 2 (SR) 2 or Cp 2 Mo 2 (CO) 2 (SR) 2 with Fe 2 (CO) 9 , Co 2 (CO) 8 , Ni(CO) 4 , Cp 2 Ni, etc. The homogeneous reactions of the cluster Cp 2 Mo 2 Co 2 S 3 (CO) 4 with thiols, thiophene, and phosphines are reviewed, as are some reactions of the clusters with metal oxide surfaces to produce heterogeneous catalysts for CO hydrogenation or hydrodesulfurization.

There are no comments yet on this publication. Be the first to share your thoughts.