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Modification of substrate reactivity using soluble polymeric supports

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
36
Issue
27
Identifiers
DOI: 10.1016/0040-4039(95)00885-g

Abstract

Abstract The effects of polymer size and solvent on the reactivity of a soluble polymer-bound substrate in heterogeneous hydrogenation reactions has been examined using PEG polymer ligands. Hydrogenation of a substrate was completely suppressed by virtue of the polymer's size and/or immiscibility with some catalysts. Changing solvents significantly perturbed reactivity of such soluble polymer-bound substrates even using Pt C .

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